Chemistry Letters p. 385 - 388 (1983)
Update date:2022-08-02
Topics:
Mukaiyama, Teruaki
Yamashita, Hiroyuki
Asami, Masatoshi
Optically active bicyclic lactones are synthesized from imides, derived from (R)-(-)-2-amino-2-phenylethanol and meso-cyclic-1,2-cis-dicarboxylic acids, by successive treatment with sodium bis(2-methoxyethoxy)aluminum hydride and sodium borohydride, followed by acid hydrolysis.This reaction is successfully applied to the asymmetric synthesis of (1R,3S)-cis-chrysanthemic acid.
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(1983)
