Electrophilic Addition of Oxygen, Sulphur, and Selenium to η2-CS2 and η2-CS2Me Cobalt Complexes

DOI: 10.1039/c39830000156

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 156 - 157 (1983)

Update date:2022-08-03

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Authors:

Bianchini, C.

Meli, A.

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Article abstract of DOI:10.1039/c39830000156

The reactions of oxygen, sulphur, and selenium with the complexes <(triphos)Co(η²-CS2)> and <(triphos)Co(η²-CS2Me)>BPh4 are described; these reactions provide evidence for the carbenoid nature of the metal-(η²-CS2) and metal-(η²-CS2Me) moieties.

Full text of DOI:10.1039/c39830000156

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