Tetrahedron p. 749 - 758 (1983)
Update date:2022-07-31
Topics:
Jalali-Naini, M.
Guillerm, D.
Lallemand, J-Y.
Isomerization by base under kinetic or thermodynamic control of the Diels-Alder adduct of 1,3,3-trimethyl-2-vinyl-1-cyclohexene with dimethyl acetylene dicarboxylate leads to two isomers which, after catalytic hydrogenation, give in high yield starting materials for synthesis of trans and cis drimanes.A short total synthesis of (+/-)-polygodial and (+/-)-drimenine from one of these isomers is desribed.
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Doi:10.1016/S0040-4020(01)91898-8
(1983)Doi:10.1039/b615940k
(2007)Doi:10.1002/open.201500059
(2015)Doi:10.1002/chem.201702930
(2017)Doi:10.1080/10426500701734398
(2008)Doi:10.1039/b506199g
(2005)
