
Journal of the Chemical Society. Chemical communications p. 6 - 8 (1980)
Update date:2022-07-29
Topics:
Primeau, John L.
Anderson, Robert C.
Fraser-Reid, Bert
The carbohydrate α-enone (1) condenses with butadiene in the presence of an excess of aluminium chloride to give the lyxo-adduct (2), exclusively, reduction of which is also stereospecific; a method has been developed to convert the product into the cyclopentanofuranoside (7).
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