Annelated Pyranosides: Some Cyclohexano- and Cyclopentano-sugars

DOI: 10.1039/c39800000006

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 6 - 8 (1980)

Update date:2022-07-29

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Authors:

Primeau, John L.

Anderson, Robert C.

Fraser-Reid, Bert

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Article abstract of DOI:10.1039/c39800000006

The carbohydrate α-enone (1) condenses with butadiene in the presence of an excess of aluminium chloride to give the lyxo-adduct (2), exclusively, reduction of which is also stereospecific; a method has been developed to convert the product into the cyclopentanofuranoside (7).

Full text of DOI:10.1039/c39800000006

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