Electronic Absorption and Circular Dichroism Spectra of the Perturbed Coplanar cis-Diene Chromophore in Deuterium- and Methyl-Substituted 7,7-Dimethylbicycloocta-2,4-dienes

DOI: 10.1021/ja00357a025

Source and publish data:

Journal of the American Chemical Society p. 6123 - 6129 (1983)

Update date:2022-08-05

Topics:

Authors:

Browne, Alan R.

Drake, Alex F.

Kearney, Francis R.

Mason, Stephen F.

Paquette, Leo A.

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Article abstract of DOI:10.1021/ja00357a025

The optically active 7,7-dimethylbicyclo<4.1.1>octa-2,4-dienes 6 and 8 have been prepared with known absolute configuratoin from (+)-nopinone.Access to their methyl congeners 7 and 9 has been achieved from (+)-α-pinene and (+)-nopinone, respectively.In 6

Full text of DOI:10.1021/ja00357a025

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