Journal of Organic Chemistry p. 3507 - 3510 (1983)
Update date:2022-08-04
Topics:
Tewson, Timothy J.
The 2,3-cyclic sulfites and sulfates of methyl 4,6-O-benzylidene-α- and -β-D-mannopyranoside were synthesized and examined as suitable substrates for the preparation of 2-deoxy-2-fluoro-D-glucose.Both sulfites on reaction with tetramethylammonium fluoride gave reaction products due to attack at sulfur by water.The methyl α-D-glycoside sulfate gave an α,β-unsaturated ketone (7).The β-methyl sulfate reacted cleanly with fluoride and other nucleophiles to give, after hydrolysis, the 2-substituted 2-deoxyglucose compounds.
View MoreKINHENG CHEMICAL(SHANGHAI)CO., LTD.
Contact:+8621-60490170
Address:Room401, No.28,Lane 189, Yangshupu Rd. Shanghai, China.
Kaiping Genuine Biochemical Pharmaceutical Co.,Ltd.
Contact:+86-750-2881198
Address:No.1, Xinke Road, Shatang Town, Kaiping, Guangdong Province, P.R.China
Contact:0792-8228321
Address:10TH Floor No.121 binjiang Road Xunyang District
KA-SHING Business Trade Macau Co., Ltd.
Contact:00853-28430045
Address:23rd Floor, Block 3 La Cite, Areia Preta, Macao
Tangshan Wisdom Trading Co.,Ltd
Contact:86 315 2222979
Address:No.41 BeiXinXi Road, Yangguang building 1-1102 , Tangshan, Hebei, China
Doi:10.1016/j.jorganchem.2016.11.005
(2017)Doi:10.1039/b506785e
(2005)Doi:10.1016/j.tetlet.2005.07.135
(2005)Doi:10.1016/j.tetlet.2005.08.096
(2005)Doi:10.1016/j.bmcl.2005.07.065
(2005)Doi:10.1021/acs.orglett.5b03591
(2016)
