Journal of Organic Chemistry p. 3507 - 3510 (1983)
Update date:2022-08-04
Topics:
Tewson, Timothy J.
The 2,3-cyclic sulfites and sulfates of methyl 4,6-O-benzylidene-α- and -β-D-mannopyranoside were synthesized and examined as suitable substrates for the preparation of 2-deoxy-2-fluoro-D-glucose.Both sulfites on reaction with tetramethylammonium fluoride gave reaction products due to attack at sulfur by water.The methyl α-D-glycoside sulfate gave an α,β-unsaturated ketone (7).The β-methyl sulfate reacted cleanly with fluoride and other nucleophiles to give, after hydrolysis, the 2-substituted 2-deoxyglucose compounds.
View MoreContact:021-50278900
Address:No.6,Room 201 ,Lane 299,bisheng road ,shanghai ,china
TAIZHOU XINGCHENG CHEMPHARM CO.,LTD.
Contact:0086-0576-88551200,88886292 ,88880039
Address:B Area. 10 Floor.Yaodadasha. 289#.Shifu Road.Taizhou.Zhejiang.China
Shenzhen JYMed Technology Co.,Ltd.
website:http://www.jymedtech.com
Contact:+86-755-26612112
Address:1#8,9/F, Biomedicine innovation Industrial Park, No.14, Jinhui Road, Pingshan Sistrict, Shenzhen, China
website:http://www.lidepharma.com
Contact:+86-25-58409506
Address:N0.2-309 2/F Chungking Express Nos.36 Nathan Road，Kowloon, HK
Contact:+86-021-50792271
Address:Building 24A, 300 Chuantu Road, Chuansha, Pudong new area, Shanghai, China, 201202
Doi:10.1016/j.jorganchem.2016.11.005
(2017)Doi:10.1039/b506785e
(2005)Doi:10.1016/j.tetlet.2005.07.135
(2005)Doi:10.1016/j.tetlet.2005.08.096
(2005)Doi:10.1016/j.bmcl.2005.07.065
(2005)Doi:10.1021/acs.orglett.5b03591
(2016)
