Organometallics p. 1466 - 1468 (1983)
Update date:2022-07-30
Topics:
Komiya, Sanshiro
Abe, Yoshihiro
Yamamoto, Akio
Yamamoto, Takakazu
A series of cis-arylmethyl(1,2-bis(dimethylphosphino)ethane)nickel(II) complexes, cis-Ni(C6H4X)-(Me)(dmpe) (X = p-OMe, p-Me, H, p-F, o-Me), has been prepared by the ligand exchange reaction of trans-Ni-(C6H4X)(Me)(PEt3)2 with a stoichiometric amount of dmpe at low temperature. Addition of phosphorus ligands such as PEt3, P(aryl)3, dmpe, P(OEt)3, and PCy3 to the complexes induces facile reductive elimination of MeC6H4X.
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Doi:10.1016/j.jorganchem.2005.03.050
(2005)Doi:10.1007/BF00506096
(1983)Doi:10.1002/jhet.5570200345
(1983)Doi:10.1021/jm050459+
(2005)Doi:10.1139/v05-088
(2005)Doi:10.1016/j.tet.2005.09.057
(2005)
