Reaction of Ziese's dimer with endo-tricyclo[3.2.1.02,4]oct-6-ene and subsequent rearrangements

DOI: 10.1021/om50004a001

Source and publish data:

Organometallics p. 1269 - 1273 (1983)

Update date:2022-08-05

Topics:

Authors:

Waddington, Mark D.

Campbell

Jennings, Paul W.

Campana, Charles F.

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Article abstract of DOI:10.1021/om50004a001

Zeise's dimer reacts rapidly with endo-tricyclo[3.2.1.0^2,4]oct-6-ene to form the nortricycloplatinacyclopentane complex 3. Further, treatment of 3 with Ph₃P effects a carbocyclic rearrangement that is analogous to a cyclopropylcarbinyl system.

Full text of DOI:10.1021/om50004a001

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