Diastereoselective zinco-cyclopropanation of chiral allylic alcohols with gem-dizinc carbenoids

DOI: 10.1021/ja054328+

Source and publish data:

Journal of the American Chemical Society p. 13140 - 13141 (2005)

Update date:2022-08-05

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Authors:

Fournier, Jean-Francois

Mathieu, Simon

Charette, Andre B.

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Article abstract of DOI:10.1021/ja054328+

The highly diastereoselective zinco-cyclopropanation of chiral allylic alcohols using gem-dizinc carbenoids is described. The reaction produces three contiguous stereogenic centers, and the resulting chiral cyclopropylzinc derivatives can be trapped with

Full text of DOI:10.1021/ja054328+

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