Bis(η-cyclopentadienyl)molybdenum Chemistry: Synthesis and Reactions of Ring-functionalised Compounds

DOI: 10.1039/DT9830000861

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 861 - 864 (1983)

Update date:2022-08-05

Topics:

Authors:

Baretta, Andre

Chong, Kenneth S.

Cloke, F. Geoffrey N.

Feigenbaum, Alexander

Green, Malcolm L. H.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9830000861

Co-condensation of molybdenum atoms with spiro<2.4>hepta-4,6-diene gives the compound .Treatment of with iodine gives the tetraiodo-derivative (2).The tetrabromo- and tetrachloro-analogues of (2) are similarly prepared.The iodo-groups of (2) can be exchanged with the SPh radical to give which reacts with hydrogen chloride to form the compound (4).Abstraction of a halide ion from (4) gives PF6.Complex (2) reacts with dimethylamine to give 2.

Full text of DOI:10.1039/DT9830000861

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:chloro[η5-(2-phenylthioethyl)cyclopentadienyl][η5-(2-phenylthioethyl)cyclopentadienyl-S]molybdenum hexafluorophosphate

Cas No:86857-58-1

R&D Labs maybe for 86857-58-1

Chinapeptides Co,. Ltd

Contact:+86-021-50792271

Address:Building 24A, 300 Chuantu Road, Chuansha, Pudong new area, Shanghai, China, 201202
Changzhou Jiana Chemical Co.,Ltd

website:http://www.jianachem.com

Contact:86-0519-88731808

Address:Zhenglu Town Wujin City, Jiangsu Province
Shandong Zhongcheng Barium Salt Co., Ltd

Contact:+86-15725732638

Address:No.29 baoxi road, hi-tech zone, zibo, shandong
Lianyungang Ningkang Chemical Co., Ltd

Contact:.+86-518-88588008

Address:http://www.chemnk.com
shanghai Tauto Biotech Co., Ltd

website:http://www.tautobiotech.com/en/index.htm

Contact:+86-21-51320588 ext. 8025

Address:No. 326, Aidisheng Rd , Zhangjiang Hi-tech Park, Shanghai , P.R.CHINA

Relevant to this article

An efficient synthesis of argifin: A natural product chitinase inhibitor with chemotherapeutic potential

Doi:10.1016/j.bmcl.2005.07.068
(2005)
Doi:10.1139/v54-005
(1954)
Heterobimetallic reductive cross-coupling of benzonitrile with carbon dioxide, pyridine, and benzophenone

Doi:10.1021/ic051320s
(2005)
Rationalisation of the stereochemical outcome of ene-reductase-mediated bioreduction of α,β-difunctionalised alkenes

Doi:10.1016/j.molcatb.2013.12.020
(2014)
Atom-economic and stereoselective syntheses of the ring A and B subunits of the bryostatins

Doi:10.1002/chem.201002930
(2011)
Organocatalytic asymmetric michael addition of 2,4-pentandione to nitroolefins

Doi:10.1021/ol0519137
(2005)

Article Doi