Bis(η-cyclopentadienyl)molybdenum Chemistry: Synthesis and Reactions of Ring-functionalised Compounds

DOI: 10.1039/DT9830000861

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 861 - 864 (1983)

Update date:2022-08-05

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Authors:

Baretta, Andre

Chong, Kenneth S.

Cloke, F. Geoffrey N.

Feigenbaum, Alexander

Green, Malcolm L. H.

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Article abstract of DOI:10.1039/DT9830000861

Co-condensation of molybdenum atoms with spiro<2.4>hepta-4,6-diene gives the compound .Treatment of with iodine gives the tetraiodo-derivative (2).The tetrabromo- and tetrachloro-analogues of (2) are similarly prepared.The iodo-groups of (2) can be exchanged with the SPh radical to give which reacts with hydrogen chloride to form the compound (4).Abstraction of a halide ion from (4) gives PF6.Complex (2) reacts with dimethylamine to give 2.

Full text of DOI:10.1039/DT9830000861

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