Asymmetric Induction at Silicon from Prochiral Silaethylenes

DOI: 10.1039/c39800000382

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 382 - 383 (1980)

Update date:2022-08-03

Topics:

Authors:

Bertrand, Guy

Dubac, Jacques

Mazerolles, Pierre

Ancelle, Jacques

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39800000382

Prochiral silaethylene intermediates react with chiral alcohols to give unequal amounts of diastereomeric pairs of alkoxysilanes (up to 30percent enantiomeric excess); this is the first example of asymmetric induction observed at a silicon centre involving a trigonal silicon species.

Full text of DOI:10.1039/c39800000382

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Ethylmethylphenylmenthoxysilan

Cas No:87037-24-9

R&D Labs maybe for 87037-24-9

Lonwin Chemical Group Limited

website:http://www.lonwinchem.com

Contact:Tel: 86-21-59858395

Address:No#966,Huaxu Road,Shanghai 201702,P.R.China
WD Silicone Co., Ltd

Contact:+86-27-87204219, +86-27-87215023

Address:2402, HuiGu Space-time Building, 8 Forest Road, East Lake Hi-Tech Development Zone
Chengdu Green Young Biopharmaceutical INC

Contact:+86-28-85337952

Address:1-B-26,Tianhe Industry Park, No.1480 of Tianfu Road,Chengdu,P.R.China,610000
Yangzhou Siyu Chemical Co.,Ltd.

Contact:+86-514-87325867 13358126196

Address:Room 620 Exposition Pavilion，No. 98 Huaihai Road,Guangling District，Yangzhou City, Jiangsu Province
Wuhan Yitongtai Science and Technology Co.,Ltd.

Contact:+86-27-88933550

Address:27th Fl. Bldg. 1, Shuian International Mansion, Heping Ave, Wuhan, Hubei, China

Relevant to this article

Ruthenium catalyzed β-selective alkylation of vinylpyridines with aldehydes/ketonesviaN₂H₄mediated deoxygenative couplings

Doi:10.1039/d0sc06586b
(2021)
A new asymmetric synthesis of (S)-dolaphenine and its heteroaromatic congeners utilizing (+)-2-hydroxy-3-pinanone and (-)-3-hydroxy-2-caranone as chiral auxiliaries

Doi:10.1016/0040-4020(95)00828-V
(1995)
Doi:10.1039/j39680000715
(1968)
Doi:10.1021/jo01268a016
(1968)
NMR investigation of platinum-diphosphine complexes in [BMIM][PF ₆] ionic liquid

Doi:10.1016/S0020-1693(03)00291-3
(2003)
Reactions of the square-planar compounds Ir(C₂Ph)L₂(PCy₃) (L₂ = 2 CO, TFB) with HSiR₃ (R = Et, Ph) and H_x+1SiPh_3-x (x = 1, 2): Stoichiometric and catalytic formation of Si-C bonds

Doi:10.1021/om950527y
(1996)

Article Doi