Asymmetric Induction at Silicon from Prochiral Silaethylenes

DOI: 10.1039/c39800000382

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 382 - 383 (1980)

Update date:2022-08-03

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Authors:

Bertrand, Guy

Dubac, Jacques

Mazerolles, Pierre

Ancelle, Jacques

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Article abstract of DOI:10.1039/c39800000382

Prochiral silaethylene intermediates react with chiral alcohols to give unequal amounts of diastereomeric pairs of alkoxysilanes (up to 30percent enantiomeric excess); this is the first example of asymmetric induction observed at a silicon centre involving a trigonal silicon species.

Full text of DOI:10.1039/c39800000382

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