Journal of the Chemical Society. Chemical communications p. 382 - 383 (1980)
Update date:2022-08-03
Topics:
Bertrand, Guy
Dubac, Jacques
Mazerolles, Pierre
Ancelle, Jacques
Prochiral silaethylene intermediates react with chiral alcohols to give unequal amounts of diastereomeric pairs of alkoxysilanes (up to 30percent enantiomeric excess); this is the first example of asymmetric induction observed at a silicon centre involving a trigonal silicon species.
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