Journal of Organic Chemistry p. 6419 - 6424 (1994)
Update date:2022-08-03
Topics:
Acena, Jose Luis
Arjona, Odon
Pradilla, Roberto Fernandez de la
Plumet, Joaquin
Viso, Alma
The total syntheses of the antibiotic component validamine 1 and its three diastereomers 2-4 have been accomplished as their racemic penta-N,O-acetates via stereocontrolled nucleophilic epoxidation of polyhydroxylated cyclohexenyl sulfones, obtained from
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