A Stereodivergent Access to Naturally Occurring Aminocarbasugars from (Phenylsulfonyl)-7-oxabicycloheptane Derivatives. Total Synthesis of Penta-N,O-acetyl-(+/-)-validamine and Its C1 and C2 Stereoisomers

DOI: 10.1021/jo00100a052

Source and publish data:

Journal of Organic Chemistry p. 6419 - 6424 (1994)

Update date:2022-08-03

Topics:

Authors:

Acena, Jose Luis

Arjona, Odon

Pradilla, Roberto Fernandez de la

Plumet, Joaquin

Viso, Alma

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Article abstract of DOI:10.1021/jo00100a052

The total syntheses of the antibiotic component validamine 1 and its three diastereomers 2-4 have been accomplished as their racemic penta-N,O-acetates via stereocontrolled nucleophilic epoxidation of polyhydroxylated cyclohexenyl sulfones, obtained from

Full text of DOI:10.1021/jo00100a052

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