Hydrolysis of Phosphate Esters Bound to Cobalt(III). Kinetics and Mechanism of Intramolecular Attack of Hydroxide on Coordinated 4-Nitrophenyl Phosphate

DOI: 10.1021/ja00363a021

Source and publish data:

Journal of the American Chemical Society p. 7327 - 7336 (1983)

Update date:2022-08-03

Topics:

Authors:

Jones, David R.

Lindoy, Leonard F.

Sargeson, Alan M.

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Article abstract of DOI:10.1021/ja00363a021

The hydrolysis of coordinated 4-nitrophenyl phosphate ester in cis-has been studied over the pH range 7-14 by 31P NMR spectroscopy and by monitoring nitrophenol release at 400 nm.Intramolecular attack by 18O labeled coordinated hyd

Full text of DOI:10.1021/ja00363a021

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