Hydrolysis of Phosphate Esters Bound to Cobalt(III). Kinetics and Mechanism of Intramolecular Attack of Hydroxide on Coordinated 4-Nitrophenyl Phosphate

DOI: 10.1021/ja00363a021

Source and publish data:

Journal of the American Chemical Society p. 7327 - 7336 (1983)

Update date:2022-08-03

Topics:

Authors:

Jones, David R.

Lindoy, Leonard F.

Sargeson, Alan M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00363a021

The hydrolysis of coordinated 4-nitrophenyl phosphate ester in cis-has been studied over the pH range 7-14 by 31P NMR spectroscopy and by monitoring nitrophenol release at 400 nm.Intramolecular attack by 18O labeled coordinated hyd

Full text of DOI:10.1021/ja00363a021

Products guided by the article

Product name:[Co(NH₂CH₂CH₂NH₂)2(OH₂)(O₃POC₆H₄NO₂)]⁽¹⁺⁾*ClO₄^(1-)*H₂O=[Co(NH₂CH₂CH₂NH₂)2(OH₂)(O₃POC₆H₄NO₂)]ClO₄*H₂O

Cas No:87183-71-9

R&D Labs maybe for 87183-71-9

Hangzhou Taiyan Trading Co., Ltd(expird)

Contact:+86-13777583958

Address:NO.63, Xingyi Street, Xihu District, Hangzhou, Zhejiang, China
Shanghai Intime pharm Co.,Ltd

Contact:86-21-58226973

Address:No 351,Guoshoujing Road, Zhangjiang Hi-tech Park, Pudong, Shanghai, China
Chiral Quest (Suzhou) Company Ltd

website:http://www.chiralquest.com

Contact:+86-0512-62956066

Address:B1/9, 218 Xinghu Street, Suzhou Industrial Park
Taizhou volsen chemical Co., Ltd

website:http://www.volsenchem.com

Contact:+86-576-88869393

Address:Jiaojiang District, Taizhou, Zhejiang, China.
Hangzhou Dingyan Chem Co., Ltd

website:http://www.dingyanchem.com

Contact:86-571-87157530

Address:RM.1118,NO.1 Building, Baiyun Tower,Jianggan Area, Hangzhou city, China,310004

Relevant to this article

Enantioselective Synthesis of Spiroindenes by Enol-Directed Rhodium(III)-Catalyzed C-H Functionalization and Spiroannulation

Doi:10.1002/anie.201507029
(2015)
SYNTHESIS OF SOME DERIVATIVES OF GLYCEROPHOSPHOCHOLINES AND THEIR INFLUENCE ON THE CYTOTOXIC ACTIVITY OF PLATELETS

Doi:10.1007/BF00780200
(1993)
Hypervalent iodine in the synthesis of bridgehead heterocycles: A new synthesis of 3,5-diarylthiazolo[2,3-c]-S-triazoles

Doi:10.1080/00397919508013857
(1995)
Surface-rolling molecules

Doi:10.1021/ja058514r
(2006)
Design of Bifunctional Dendritic 5-Aminolevulinic Acid and Hydroxypyridinone Conjugates for Photodynamic Therapy

Doi:10.1021/acs.bioconjchem.8b00574
(2018)
Asymmetric michael reactions on polymeric support: Auxiliary immobilization and stereoselective construction of quaternary stereocenters

Doi:10.1002/ejoc.200500450
(2005)

Article Doi