Tetrahedron Letters p. 6827 - 6830 (1996)
Update date:2022-08-05
Topics:
Gonzales, Stephen S.
Jacobs, Hollie K.
Juarros, LuAnne E.
Gopalan, Aravamudan S.
Carbonate and acyl derivatives of 3-arylsulfonylcyclohexanols and heptanols, upon deprotonation with LHMDS in THF at -78°C, undergo an intramolecular cyclization reaction to give bicyclic lactones or the corresponding acyl transfer products in synthetically useful yields. In contrast, the corresponding cyclopentyl derivatives show different reactivity.
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