N-PROPARGYLAMINOPHOSPHINES. A NOVEL REARRANGEMENT OF PROPARGYLHETEROATOM SUBSTITUTED TRIVALENT PHOSPHORUS COMPOUNDS

DOI: 10.1016/S0040-4039(00)81733-5

Source and publish data:

Tetrahedron Letters p. 1643 - 1646 (1983)

Update date:2022-08-03

Topics:

Authors:

Angelov, Christo M.

Dahl, Otto

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Article abstract of DOI:10.1016/S0040-4039(00)81733-5

N-Methyl-N-propargylaminodiethylphosphine rearranges spontaneously with P-N bond cleavage to N-methyl-Z-3-diethylphosphino-2-propenal imine; the corresponding aminodiphenylphosphine behaves similarly but trivalent propargylamino dialkyloxy or diamino phosphorus compounds are stable.

Full text of DOI:10.1016/S0040-4039(00)81733-5

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