REACTIONS OF 4,5-DINITROIMIDAZOLE AND 4(5)-NITROIMIDAZOLE-5(4)-SULFONIC ACID WITH NUCLEOPHILES

DOI: 10.1007/BF00523079

Source and publish data:

Chemistry of Heterocyclic Compounds p. 650 - 652 (1983)

Update date:2022-08-04

Topics:

Authors:

Mokrushin, V. S.

Belyaev, N. A.

Kolobov, M. Yu.

Fedotov, A. N.

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Article abstract of DOI:10.1007/BF00523079

The reactions of 4,5-dinitroimidazole and 5(4)-nitroimidazole-4(5)-sulfonic acid with nucleophilic agents were studied.Mercapto-, alkoxy-, and aminonitroimidazoles were synthesized.In the reaction of dinitroimidazole with sodium alkoxides 5(4)-nitroimidazole was obtained in addition to alkoxynitroimidazoles.It is shown that in the formation of salts of the starting imidazoles with bases nucleophilic-substitution reactions take place only with "soft" reagents.

Full text of DOI:10.1007/BF00523079

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