Chemistry of Heterocyclic Compounds p. 650 - 652 (1983)
Update date:2022-08-04
Topics:
Mokrushin, V. S.
Belyaev, N. A.
Kolobov, M. Yu.
Fedotov, A. N.
The reactions of 4,5-dinitroimidazole and 5(4)-nitroimidazole-4(5)-sulfonic acid with nucleophilic agents were studied.Mercapto-, alkoxy-, and aminonitroimidazoles were synthesized.In the reaction of dinitroimidazole with sodium alkoxides 5(4)-nitroimidazole was obtained in addition to alkoxynitroimidazoles.It is shown that in the formation of salts of the starting imidazoles with bases nucleophilic-substitution reactions take place only with "soft" reagents.
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