
Tetrahedron Letters p. 3733 - 3736 (1983)
Update date:2022-08-03
Topics:
Hori, Mikio
Kataoka, Tadashi
Shimizu, Hiroshi
Kataoka, Masahiro
Tomoto, Akihiko
Kishida, Masato
The thermal reaction of 1-cyano-2-methyl-3,4-dihydro-2-thianaphthalene (3a) in toluene afforded 1-benzyl-1-cyano-2-thiochroman (6a) together with 1-cyano-1-methyl-2-thiochroman (4a), whereas the thermal reaction in ethanol gave the spiro-compound (8a) in 82.7percent yield.The structure of the spiro-compound was established by their spectral data and chemical reactions.
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