Ring Expansion of Aziridines to Piperidines using the Aza-Wittig Rearrangement

DOI: 10.1016/0040-4039(95)00557-S

Source and publish data:

Tetrahedron Letters p. 3557 - 3560 (1995)

Update date:2022-07-29

Topics:

Authors:

Coldham, Iain

Collis, Alan J.

Mould, Roger J.

Rathmell, Richard E.

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Article abstract of DOI:10.1016/0040-4039(95)00557-S

A one-pot, two-step synthesis of unsaturated piperidines from 2-keto aziridines is reported.Treatment of a range of 2-keto aziridines with two equivalents of a phosphonium ylide generates intermediate vinyl aziridines which rearrange by a <2,3>-sigmatropi

Full text of DOI:10.1016/0040-4039(95)00557-S

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