
Tetrahedron Letters p. 3557 - 3560 (1995)
Update date:2022-07-29
Topics:
Coldham, Iain
Collis, Alan J.
Mould, Roger J.
Rathmell, Richard E.
A one-pot, two-step synthesis of unsaturated piperidines from 2-keto aziridines is reported.Treatment of a range of 2-keto aziridines with two equivalents of a phosphonium ylide generates intermediate vinyl aziridines which rearrange by a <2,3>-sigmatropi
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