The role of the hydrogen bonding in cycloadditions of benzonitrile oxide with cyanophenols

DOI: 10.1016/0040-4020(96)00359-6

Source and publish data:

Tetrahedron p. 7885 - 7892 (1996)

Update date:2022-08-03

Topics:

Authors:

Corsaro, Antonino

Buemi, Giuseppe

Chiacchio, Ugo

Perrini, Giancarlo

Pistara, Venerando

Romeo, Roberto

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Article abstract of DOI:10.1016/0040-4020(96)00359-6

The reactivity of aromatic nitriles in cycloadditions with benzonitrile oxide is remarkably enhanced by the ortho-hydroxy substituent. Semiempirical PM3 calculations are in agreement with a hydrogen bonding effect.

Full text of DOI:10.1016/0040-4020(96)00359-6

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