Slip - Inversion - Slip mechanism of phosphametallocene isomerization. Spectroscopic characterization of an (η1-phospholyl)titanium complex. Synthesis and structures of chiral mono(phospholyl)titanium complexes

DOI: 10.1021/om050357h

Source and publish data:

Organometallics p. 1079 - 1083 (2006)

Update date:2022-08-03

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Authors:

Ahn, Yi Joon

Rubio, Ramel J.

Hollis, T.Keith

Tham, Fook S.

Donnadieu, Bruno

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Article abstract of DOI:10.1021/om050357h

The first reported synthesis and spectroscopic characterization of a group 4 η¹-phospholyl complex, (η¹-dibenzophospholyl) tris(dimethylamido)titanium, are documented, which has an η¹- phospholyl ligand analogous to those proposed in the slip - inversion - slip mechanism of phosphametallocene isomerization.

Full text of DOI:10.1021/om050357h

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