Synthesis of (+/-)-Depentylperhydrohistrionicotoxin

DOI: 10.1039/P19830002383

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 2383 - 2386 (1983)

Update date:2022-08-04

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Authors:

Carruthers, William

Cumming, S. Andrew

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Article abstract of DOI:10.1039/P19830002383

Palladium(0)-catalysed cyclisation of 3-acetoxy-1-(4-aminoalkyl)cyclohexenes provides convenient access to the 1-azaspiro<5.5>undecane ring system found in the histrionicotoxins.Hydroboration of the 7-butyl derivative (4; R¹ = Buⁿ, R

Full text of DOI:10.1039/P19830002383

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