Synthesis and Reactivity of Cyclonickelated Compounds. Crystal and Molecular Structure of 2

DOI: 10.1039/c39830000928

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 928 - 929 (1983)

Update date:2022-08-03

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Authors:

Arlen, Christian

Pfeffer, Michel

Fischer, Jean

Mitschler, Andre

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Article abstract of DOI:10.1039/c39830000928

o-N,N-Dimethylaminobenzyl-lithium reacted with NiCl2(PR3)2 to give cyclonickelated compounds; hexafluorobut-2-yne was inserted into their Ni-C bonds giving rise to a seven-membered organometallic ring when the phosphine was PMe3, whereas in the case of PEt3 a dimeric compound was obtained.

Full text of DOI:10.1039/c39830000928

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