Journal of the Chemical Society. Chemical communications p. 928 - 929 (1983)
Update date:2022-08-03
Topics:
Arlen, Christian
Pfeffer, Michel
Fischer, Jean
Mitschler, Andre
o-N,N-Dimethylaminobenzyl-lithium reacted with NiCl2(PR3)2 to give cyclonickelated compounds; hexafluorobut-2-yne was inserted into their Ni-C bonds giving rise to a seven-membered organometallic ring when the phosphine was PMe3, whereas in the case of PEt3 a dimeric compound was obtained.
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