Fluorine segregation in crystalline materials: Structural control and solid-state [2+2] cycloaddition in CF3-substituted tetrathiafulvalene derivatives

Article abstract of DOI:10.1002/chem.200501078

The well-known influence of long perfluorinated chains on the structures and stability of amphiphilic molecules in liquid crystalline mesophases or mesoscopic micellar arrangements is evaluated here in the realm of crystalline materials based on rigid aro