PROTON-INDUCED DIMERISATION AND RELATED REACTIONS OF MONONUCLEAR TUNGSTEN CARBYNE COMPLEXES

DOI: 10.1016/S0022-328X(00)99266-0

Source and publish data:

Journal of Organometallic Chemistry p. C37 - C40 (1983)

Update date:2022-08-05

Topics:

Authors:

Jeffery, John C.

Laurie, Jill C. V.

Moore, Iain

Stone, F. Gordon A.

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Article abstract of DOI:10.1016/S0022-328X(00)99266-0

The products obtained by treating the compounds CR)(CO)2(η-C5H5)> (R=C6H4Me-4 or Me) with HBF4*Et2O or with HI are described and compared with species obtained by protonating or methylating the complexes 2-C(R)C(O)>(CO)(PMe3)(η-C5H5)>

Full text of DOI:10.1016/S0022-328X(00)99266-0

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Product name:W(C₂(OCH₃)(C₆H₄CH₃))(CO)(P(CH₃)3)(C₅H₅)⁽¹⁺⁾*SO₃CF₃^(1-)=(W(C₂(OCH₃)(C₆H₄CH₃))(CO)(P(CH₃)3)(C₅H₅))(SO₃CF₃)

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