CYCLOPALLADATED PRIMARY, SECONDARY AND TERTIARY BENZYLAMINES, AND BENZALIMINES. A NEW METHOD OF SYNTHESIS

Article abstract of DOI:10.1016/0022-328X(83)87171-X

Cyclopalladated complexes of primary, secondary and tertiary benzylamines and of benzalimines have been prepared by the oxidative addition of the corresponding ortho-bromobenzylamine and ortho-halobenzalimine to bis(dibenzylideneacetone)palladium(0).The complexes have been characterised fully as the monomeric triphenylphosphine derivatives.