Tetrahedron Letters p. 181 - 184 (1984)
Update date:2022-08-05
Topics:
Adam, Waldemar
Hannemann, Klaus
Hoessel, Peter
Photo-extrusion of nitrogen from the azoalkane 1 in the presence of molecular oxygen gave besides the hydrocarbons 3 and 5, the endoperoxide 10 and hydroperoxide 11, the former via trapping of the 1,4-diradical 4 by triplet oxygen, the latter by ene-reaction of hydrocarbon 5 with singlet oxygen.
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