Neighboring Group Participation by Pyridine Rings and N-Oxides. Synthesis and Solvolysis of 5,8-Dihydro-5,8-methanoisoquinoline Derivatives

DOI: 10.1021/jo00188a003

Source and publish data:

Journal of Organic Chemistry p. 2527 - 2533 (1984)

Update date:2022-08-05

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Authors:

Tanida, Hiroshi

Irie, Tadashi

Hayashi, Yoko

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Article abstract of DOI:10.1021/jo00188a003

Cycloaddition of cyclopentadiene with glutinic acid (3) followed by multistep synthesis gave 5,8-dihydro-5,8-methanoisoquinoline (13) and its N-oxide (14): The alcohols for solvolyses were prepared by hydroboration.Rate and product studies were carried ou

Full text of DOI:10.1021/jo00188a003

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