NEW STEREO- AND REGIOSPECIFIC SYNTHESIS OF HUMULENE BY MEANS OF THE PALLADIUM CATALYZED CYCLIZATION OF HALOALKENYLBORANES

DOI: 10.1016/S0040-4039(01)80019-8

Source and publish data:

Tetrahedron Letters p. 761 - 764 (1984)

Update date:2022-07-29

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Authors:

Miyaura, Norio

Suginome, Hiroshi

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Article abstract of DOI:10.1016/S0040-4039(01)80019-8

We describe a new stereo- and regiospecific synthesis of humulene, the major sesquiterpene of hops, by means of the palladium-catalyzed cyclization of haloalkenylboranes derived from geranyl halides via 4 principal steps.

Full text of DOI:10.1016/S0040-4039(01)80019-8

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