Tetrahedron Letters p. 761 - 764 (1984)
Update date:2022-07-29
Topics:
Miyaura, Norio
Suginome, Hiroshi
We describe a new stereo- and regiospecific synthesis of humulene, the major sesquiterpene of hops, by means of the palladium-catalyzed cyclization of haloalkenylboranes derived from geranyl halides via 4 principal steps.
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