NEW STEREO- AND REGIOSPECIFIC SYNTHESIS OF HUMULENE BY MEANS OF THE PALLADIUM CATALYZED CYCLIZATION OF HALOALKENYLBORANES

DOI: 10.1016/S0040-4039(01)80019-8

Source and publish data:

Tetrahedron Letters p. 761 - 764 (1984)

Update date:2022-07-29

Topics:

Authors:

Miyaura, Norio

Suginome, Hiroshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)80019-8

We describe a new stereo- and regiospecific synthesis of humulene, the major sesquiterpene of hops, by means of the palladium-catalyzed cyclization of haloalkenylboranes derived from geranyl halides via 4 principal steps.

Full text of DOI:10.1016/S0040-4039(01)80019-8

Products guided by the article

Product name:Silane, [4,8-dimethyl-1-(2-methyl-1-propenylidene)-3,7-nonadienyl]trimethyl-, (E)-

Cas No:90544-11-9

R&D Labs maybe for 90544-11-9

NEW FORTUNE INDUSTRIAL CO.,LTD.

website:http://newfortune.lookchem.com/

Contact:+86-25-8645-9456

Address:C4-105 GREEN ISLAND FLOWER TOWN
Luoyang Aoda chemical Co.,Ltd.

Contact:+86-379-67518785 67516588

Address:MiaoWan industry district,YanShi City,Henan,China
Zhejiang Haizhou Pharmaceutical Co., Ltd.

website:https://www.haizhoupharma.com/

Contact:+86-576-88221016

Address:No. 19, Donghai 5th Avenue, Yanhai Industrial Zone, Linhai, Zhejiang, China
Changzhou Anyi Biochem Co., Ltd.(expird)

Contact:+86-519-88836158

Address:no,51 caoda
Tianjin Jingye Fine Chemicals Co., Ltd.

Contact:+86-15722078107; +86-22-26911407

Address:Bohua Fine Chemicals Base of Petrochemical Industry Park, Nanhuan Road, Dagang District, Tianjin, 300271, P. R. China

Relevant to this article

Optimization of α-ketoamide based p38 inhibitors through modifications to the region that binds to the allosteric site

Doi:10.1016/j.bmcl.2010.06.102
(2010)
Synthesis and pharmacochemical study of novel polyfunctional molecules combining anti-inflammatory, antioxidant, and hypocholesterolemic properties

Doi:10.1016/j.bmcl.2005.11.027
(2006)
Synthesis of isotopically labeled all-trans retinals for DNP-enhanced solid-state NMR studies of retinylidene proteins

Doi:10.1002/jlcr.3576
(2018)
Cryovoltammetrically probing functional group reductive cleavage: Alkyl-sulfur versus aryl-sulfur bond cleavage in an alkyl naphthyl thioether under single electron-transfer is temperature switchable

Doi:10.1039/b606638k
(2006)
Molecular tongs containing amino acid mimetic fragments: New inhibitors of wild-type and mutated HIV-1 protease dimerization

Doi:10.1021/jm060576k
(2006)
Discovery and SAR of cinnolines/quinolines as liver X receptor (LXR) agonists with binding selectivity for LXRβ

Doi:10.1016/j.bmc.2009.04.012
(2009)

Article Doi