Tetrahedron p. 5779 - 5790 (1985)
Update date:2022-08-04
Topics:
Goliaszewski, Alan
Schwartz, Jeffrey
Bis(allylic)palladium complexes can be induced to undergo reductive elimination by replacement of phosphine ligands in the system with ?-acidic ligands.The product 1,5-dienes, formed in high yield, are predominantly the 'head-to-head' coupled isomers.The bis(allylic)palladium intermediates may be formed by addition of an allylic Grignard or trialkyl(allylic)tin reagent to an(η3-allyl)palladium chloride complex, or by 1,3-diene condensation.The latter process leads to cyclodimerization, 'unusual' for palladium catalysed reactions.
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Doi:10.1021/ja0581346
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(2001)Doi:10.1039/b605253c
(2006)Doi:10.1055/s-2006-941603
(2006)Doi:10.1021/ja0642360
(2006)Doi:10.1021/jm050849w
(2006)
