Synthesis and Highly Regioselective Diels-Alder Reaction of Functionalized Isoprenes Involving a Terminal Alkoxy Group and Chemical Modification of the Resulting Adducts.

DOI: 10.1021/jo00193a028

Source and publish data:

Journal of Organic Chemistry p. 3595 - 3600 (1984)

Update date:2022-08-02

Topics: Synthesis Chemical modification Diels-Alder Reaction Highly Regioselective

Authors:

Mandai, Tadakatsu

Osaka, Kazuhito

Kawagishi, Makoto

Kawada, Mikio

Otera, Junzo

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Article abstract of DOI:10.1021/jo00193a028

A variety of functionalized isoprenes involving a terminal alkoxy group (2 and 3) were newly synthesized according to eq 1, 2, and 3.These compounds proved to undergo a cycloaddition with various unsymmetric dienophiles highly regioselectively without a L

Full text of DOI:10.1021/jo00193a028

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