Tetrahedron p. 1975 - 1982 (1984)
Update date:2022-07-29
Topics:
Guinaudeau, Helene
Freyer, Alan J.
Shamma, Maurice
Baser, Kemal Husnu Can
The new bisbenzylisoquinolines (+)-thaligrisine and (+)-thaliphylline 6 have been isolated from Thalictrum minus var. microphyllum.Four rules are described which correlate the structures os Thalictrum bisbenzylisoquinolines with their stereochemistry at C-1 and C-1'.As a result, (+)-thalrugosamine is shown to be identical with (+)-homoaromoline 14. (+)-Thalisamine and (+)-N'-norhernandezine are also identical and are represented by expression 18.The sole exception to the rules is (-)-isothalidezine 15.
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Doi:10.1021/je60022a021
(1964)Doi:10.1002/jps.2600830722
(1994)Doi:10.1055/s-2006-950433
(2006)Doi:10.1039/b911999j
(2009)Doi:10.1039/c8ta04901g
(2018)Doi:10.1021/acs.oprd.7b00378
(2018)