Bulletin of the Chemical Society of Japan p. 2040 - 2044 (1989)
Update date:2022-08-02
Topics:
Matsubara, Yoshiharu
Matsui, Shuichi
Takekuma, Shin-ichi
Quo, Yan Pin
Yamamoto, Hiroshi
Nozoe, Tetsuo
Oxidation of guaiazulene (1) with peracetic acid in hexane at 25 deg C afforded as high as an 80percent yield of the title biguaiazulenedione (12), which upon heating at 60 deg C under nitrogen gave the title 1-azulenone (13) quantitatively.Oxidation of 12 and 13 was studied under various conditions, and these compounds were shown to be highly important key intermediates for a large number of the complex products obtained by autoxidation of 1.
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