Journal of the Chemical Society. Perkin transactions II p. 875 - 878 (1984)
Update date:2022-09-26
Topics:
Katritzky, Alan R.
Mokrosz, Jerzy L.
Lopez-Rodriguez, Maria L.
The title pyrylium salt reacts with lysine residues in gelatin and chymotrypsin in aqueous buffer to form rapidly the corresponding divinylogous amide and pseudobase in a ratio depending on the protein concentration.First-order ring closure of the divinylogous amide proceeds at rates comparable to those observed with the analogous intermediate from free lysine.
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