New Bimetallic, Phosphido-bridged Iron Complexes derived from 2-

DOI: 10.1039/c39840000653

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 653 - 655 (1984)

Update date:2022-08-05

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Authors:

Yu, Yuan-Fu

Gallucci, Judith

Wojcicki, Andrew

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Article abstract of DOI:10.1039/c39840000653

The title dianion, obtained by deprotonation of - at low temperature, affords various phosphido-bridged di-iron complexes upon reaction with iodohydrocarbons; new complexes include - (R = Me, Et, Prⁿ, Prⁱ, allyl), Fe2(μ-PPh2)<μ-C(R)O>(CO)5(PPh2R) (R = Prⁿ, Prⁱ), Fe2(μ-PPh2)(CO)5(η³-C3H5)(PPh2C3H5), the structure of which was determined by X-ray diffraction, and Fe2(μ-PPh2)(μ-CH2PPh2)(CO)6.

Full text of DOI:10.1039/c39840000653

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