Acylphosphonates. 5. A new method for Stereospecific Generation of Phosphorothioate via Aroylphosphonate Intermediate

DOI: 10.1016/S0040-4039(00)84142-8

Source and publish data:

Tetrahedron Letters p. 935 - 938 (1986)

Update date:2022-08-04

Topics:

Authors:

Fujii, Mitsuo

Ozaki, Kouji

Kume, Akiko

Sekine, Mitsuo

Hata, Tsujiaki

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)84142-8

Dideoxynucleoside phosphorothioates were synthesized by a new mwthod via dideoxynucleoside aroylphosphonates.The aroyl groups were easily removed from 1 and 2 by the action of n-BuNH₂ and in situ converted to only one diastereomer (Rp configura

Full text of DOI:10.1016/S0040-4039(00)84142-8

Products guided by the article

Product name:(S)-Thiophosphoric acid O-[(2R,3S,5R)-5-(6-amino-purin-9-yl)-2-hydroxymethyl-tetrahydro-furan-3-yl] ester O'-[(2R,3S,5R)-3-hydroxy-5-(5-methyl-2,4-dioxo-3,4-dihydro-2H-pyrimidin-1-yl)-tetrahydro-furan-2-ylmethyl] ester

Cas No:92217-09-9

R&D Labs maybe for 92217-09-9

CHEMINN LTD.

website:http://www.cheminn.com/

Contact:86-531-67875205

Address:No.9-2,South of Shanda Road, Jinan ,China
Nanyang Tianhua pharmaceutical Co.,Ltd.

Contact:+8618639816203

Address:Longsheng Industrial Park
SuZhou LaiTeou

Contact:+86-0512-88957371

Address:shanghai
Zhejiang Linhai Xinhua Chemicals Factory

Contact:0086-13661858911

Address:Xunqiao Development Zone, Linhai, Zhejiang, China
Changzhou Hopschain Chemical Co.,Ltd

website:http://www.hopschem.cn/products.html

Contact:86-519-85528066

Address:Room 710, Unit A, Xingbei Development Mansion, Tongjiang Road, Changzhou City,213000, China

Relevant to this article

Synthesis and Diels-Alder Reactions of 1,3-Dimethyl-4-(phenylsulfonyl)-4H-furo<3,4-b>indole. A new Annulation Strategy for the Construction of Ellipticine and Isoellipticine

Doi:10.1021/jo00197a039
(1984)
A Metal-Free Route to Heterocyclic Trifluoromethyl- and Fluoroalkylselenolated Molecules

Doi:10.1021/acs.orglett.7b03338
(2018)
Novel palladium complexes employing mixed phosphine phosphonates and phosphine phosphinates as anionic chelating [P,O] ligands

Doi:10.1039/b612694d
(2007)
Selective Aromatic Hydroxylation with Dioxygen and Simple Copper Imine Complexes

Doi:10.1002/chem.201501003
(2015)
Ultrafast and ultraslow oxygen atom transfer reactions between late metal centers

Doi:10.1021/ja065713h
(2007)
Phosphonate-Phosphate- and Phosphate-Phosphonate-Rearrangement and Its Application, Part II: Stereochemistry of Phosphonate-Phosphate-Rearrangement at Carbon as Exemplified by the Isomerisation of (R)-(+)- and (S)-(-)-(1-Hydroxy-1-phenylethyl)phosphonic Acid Diethylester

Doi:10.1007/BF00814152
(1993)

Article Doi