Acylphosphonates. 5. A new method for Stereospecific Generation of Phosphorothioate via Aroylphosphonate Intermediate

DOI: 10.1016/S0040-4039(00)84142-8

Source and publish data:

Tetrahedron Letters p. 935 - 938 (1986)

Update date:2022-08-04

Topics:

Authors:

Fujii, Mitsuo

Ozaki, Kouji

Kume, Akiko

Sekine, Mitsuo

Hata, Tsujiaki

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Article abstract of DOI:10.1016/S0040-4039(00)84142-8

Dideoxynucleoside phosphorothioates were synthesized by a new mwthod via dideoxynucleoside aroylphosphonates.The aroyl groups were easily removed from 1 and 2 by the action of n-BuNH₂ and in situ converted to only one diastereomer (Rp configura

Full text of DOI:10.1016/S0040-4039(00)84142-8

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