Carbohydrate Research p. 21 - 30 (1988)
Update date:2022-08-02
Topics:
Brimacombe, John S.
Kabir, Abul K. M. S.
The stereochemistry of the major osmylation products of carbohydrate-based allylic alcohols can usually be predicted by application of Kishi's empirical rule.In particular, the addition of OsO4 can be formulated as taking place in the more abundant conformation on the surface anti to a pyranose or furanose ring-oxygen atom located at a stereocentre adjacent to the olefinic linkage.Exceptions to Kishi's empirical rule for osmylation are sometimes encountered with conjugated carbonyl compounds.
View MoreContact:0833-5590788/5590338/5590055
Address:Victory in the town of Red Star Village,Mount Emei City,industrial concentration area storage processing logistics parkpark
LianYunGang Chiral Chemical(CHINA) CO.,LTD
Contact:+86-518-83616958 +86-519-82884848
Address:LianYunGang Chemical Industry Park (JiangSu)
website:http://www.china-sinoway.com
Contact:+86-592-5853819
Address:16/F,Huicheng Comm,Complex,No839 XiaHe Rd, Xiamen,China
Contact:+31-24-3886056
Address:Binderskampweg 29 Unit 36
Shanghai Forever Biotech Co., Ltd.
Contact:+86-21-69734790
Address:Room 5017/5019、5022、5024 of Technology Innovation Centre, No.1155, Gongyuan East Rd, QingPu District, Shanghai China.
Doi:10.1002/hlca.19610440502
(1961)Doi:10.1080/00397919808003069
(1998)Doi:10.1002/chem.200600861
(2006)Doi:10.1016/S0040-4039(01)81319-8
(1984)Doi:10.1002/anie.201702304
(2017)Doi:10.1021/jm00053a016
(1993)