Novel Organosulfur Metal Complexes Derived from Dithioesters

DOI: 10.1021/ja00287a031

Source and publish data:

Journal of the American Chemical Society p. 173 - 179 (1985)

Update date:2022-08-02

Topics:

Authors:

Alper, Howard

Einstein, Frederick W. B.

Hartstock, Frederick W.

Willis, Anthony C.

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Article abstract of DOI:10.1021/ja00287a031

Dithioesters react with complexes containing a metal-metal triple bond, in refluxing toluene or xylene, to give a novel class of organosulfur complexes.A single-crystal X-ray analysis of one such complex <(CH3C5H4)2Mo2(CO)2(SCCH3)(SC2H5)> confirms the presence of a symmetrically bridging thioacyl function, a bridging thioalkyl group, and a molybdenum-molybdenum single-bond distance of 2.806(1) Angstroem.When the reaction was effected at room temperature, a complex with a retained dithioester unit was obtained.As established by an X-ray analysis of , the thiocarbonyl group is bonded to one molybdenum atom with the sulfur atom also donor bound to the other metal atom.A semibridging carbonyl group is also present.

Full text of DOI:10.1021/ja00287a031

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