ENHANCEMENT OF ERYTHRO-SELECTIVITY IN THE -WITTIG REARRANGEMENT OF CROTYL PROPARGYL ETHER SYSTEM AND ITS USE IN THE STEREOCONTROLLED FORMAL SYNTHESIS OF (+/-)-OUDEMANSIN

DOI: 10.1246/cl.1983.1379

Source and publish data:

Chemistry Letters p. 1379 - 1382 (1983)

Update date:2022-07-29

Topics:

Authors:

Mikami, Koichi

Azuma, Ken-ichi

Nakai, Takeshi

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Article abstract of DOI:10.1246/cl.1983.1379

The <2,3>-Wittig variant of (Z)-crotyl ether involving trimethylsilylethynyl (or 1-propynyl) group as the key substituent on the carbanion terminus exhibits an exceptionally high level of erythro-selection, and its synthetic potential is illustrated in th

Full text of DOI:10.1246/cl.1983.1379

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