Journal of Organic Chemistry p. 4872 - 4876 (1984)
Update date:2022-08-02
Topics:
White, Emil H.
Reefer, John
Erickson, Ronald H.
Dzadzic, Petar M.
Nitration of N-alkyl-O-benzoylhydroxylamines yields the correspondng N-nitro derivatives.At modest temperatures these compounds decompose to yield alkyl benzoates, alkenes, benzoic acid, and nitrous oxide.In the case of primary alkylnitrohydroxylamines, nitroalkanes and alkyl nitrates are also formed.The alkyl benzoates are products of ionic reactions since skeletal rearrangements characteristics of carbonium ions occur.The insensivity of the rates of decomposition to solvent polarity suggests that the rate-determining step is a rearrangement rather than direct ionization.
View MoreJiangsu Willing Bio-Tech Co ltd
website:http://www.willingbio.com/
Contact:+86 18796909136--
Address:No 18 Guoqiao Road
Xi'an caijing Opto-Electrical Science & Technology Co., LTD
Contact:+86-29-88294447
Address:NO.168 Zhangba Rd. East, Xi'an, P.R.China
Shanghai KFSL Pharmaceutical Technology Co.,Ltd.
Contact:+86-21-39971718
Address:859 jiadingchengliu shanghai
Contact:027-87677569
Address:Room 2203, yujingmingmen Buidling One, xiongchu Road, wuhan city, hubei province, China
Contact:0086 533 2282832
Address:Zibo,Shandong
Doi:10.1016/S0040-4039(01)81257-0
(1984)Doi:10.1021/ja01133a535
(1952)Doi:10.1016/j.tet.2009.10.042
(2009)Doi:10.1021/jo062228w
(2007)Doi:10.1021/jm00336a041
(1964)Doi:10.1246/bcsj.60.2197
(1987)