A NEW SYNTHETIC METHOD FOR THE FRAMEWORK OF ASPIDOSPERMA ALKALOIDS USING SINGLET OXYGEN CHEMISTRY

DOI: 10.1016/S0040-4020(01)96582-2

Source and publish data:

Tetrahedron p. 2115 - 2124 (1985)

Update date:2022-07-30

Topics:

Authors:

Natsume, Mitsutaka

Utsunomiya, Iwao

Yamaguchi, Keiichiro

Sakai, Shin-Ichiro

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Article abstract of DOI:10.1016/S0040-4020(01)96582-2

A singlet oxygen adduct of 1-benzyloxycarbonyl-1,2-dihydro-5-(2-methyl-1,3-dioxolan-2-yl)pyridine (21) was treated with indole in the presence of stannous chloride to yield directly the complex compound 22, which will act as a suitable starting material f

Full text of DOI:10.1016/S0040-4020(01)96582-2

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Product name:1(2H)-Pyridinecarboxylic acid, 5,6-dihydro-5-hydroxy-2-(1H-indol-3-yl)-3-(2-methyl-1,3-dioxolan-2-yl)-, phenylmethyl ester, trans-

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