Tetrahedron p. 3975 - 3992 (1989)
Update date:2022-08-03
Topics:
Lounasmaa, Mauri
Jokela, Reija
Stereochemical control in the preparation of 2-substituted 1,2,3,4,6,7,12,12b-octahydroindolo<2,3-a>quinolizines possessing at will the C(12b)H-C(2H) cis or trans configuration was achieved by catalytic reduction of the 2,3-dehydro analoques, which were either unsubstituted on the indole nitrogen or substituted with a BOC-group, respectively.The contribution of different conformations to the conformational equilibrium of the prepared compounds was estimated by 13C NMR spectral analysis.
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