Organometallics p. 398 - 400 (1985)
Update date:2022-09-26
Topics:
Seyferth, Dietmar
Womack, Gary B.
Dewan, John C.
The reaction of Fe3(CO)12 with mercaptans (RSH, R = Et, Me3C) in the presence of stoichiometric Et3N in THF gives the reactive salt [Et3NH+][(μ-RS)(μ-CO)Fe2(CO) 6-]. Reactions of the latter with benzoyl and acetyl chloride, diphenylchlorophosphine, allyl chloride, and propargylic halides have been studied. New bridging ligands (μ-RC=O, μ-Ph2P, μ-C3H6, μ-η1, η2-allenyl) were introduced between the iron atoms in all of these reactions. X-ray crystal structures of (μ-EtS)(μ-C3H6)Fe2(CO)6 and (μ-Me3CS)(μ-η1,η2-CH=C=CH 2)Fe(CO)6 were determined.
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