Silyl Ketone Chemistry. Preparation of Eremophilane and Eudesmane Sesquiterpenes by Vinylallene Cycloaddition

DOI: 10.1021/jo00200a065

Source and publish data:

Journal of Organic Chemistry p. 5282 - 5283 (1984)

Update date:2022-08-04

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Authors:

Reich, Hans J.

Eisenhart, Eric K.

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Article abstract of DOI:10.1021/jo00200a065

The Diels-Alder cyclization of enone siloxyvinylallenes leading to dehydrofukinone and selina-4(14),7(11)-dien-8-one are described.Several silyl ketone (acylsilane) reactions were used to prepare key enol silyl ether intermediates.

Full text of DOI:10.1021/jo00200a065

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