Silyl Ketone Chemistry. Preparation of Eremophilane and Eudesmane Sesquiterpenes by Vinylallene Cycloaddition

DOI: 10.1021/jo00200a065

Source and publish data:

Journal of Organic Chemistry p. 5282 - 5283 (1984)

Update date:2022-08-04

Topics:

Authors:

Reich, Hans J.

Eisenhart, Eric K.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00200a065

The Diels-Alder cyclization of enone siloxyvinylallenes leading to dehydrofukinone and selina-4(14),7(11)-dien-8-one are described.Several silyl ketone (acylsilane) reactions were used to prepare key enol silyl ether intermediates.

Full text of DOI:10.1021/jo00200a065

Products guided by the article

Product name:{[(1E,5E)-7-(tert-Butyl-dimethyl-silanyloxy)-1-isopropenyl-9-methyl-deca-1,5,7,8-tetraenyloxy]-dimethyl-silanyl}-benzene

Cas No:93782-80-0

R&D Labs maybe for 93782-80-0

Tai zhou world Pharm & Chem Co., Ltd

Contact:+86-576-85301198

Address:Rome 1001,wangjiang plaza,unti 2,jinshan east Road linhai,zhejiang,china
Nanjing Chemlin Chemical Co., Ltd.

website:http://www.echemlin.cn

Contact:+86-25-83697070

Address:Rm.902 Longyin Plaza, No. 217 Zhongshan Rd.(N) Nanjing 210009,China
SHANDONG CREDAGRI CHEMICAL CO., LTD.

Contact:+86-531-88872050

Address:ROOM 601A, BUILDING 2, SHUNTAI SQUARE, NO. 2000 SHUNHUA ROAD, HI-TECH DEVELOPMENT ZONE, JINAN, CHINA.
Fusilin chemical science & technology co., ltd.

Contact:532-80698166/86057573, +86-400-669-7885

Address:School of Material Science & Engineering, Shandong Uinversity of Science & Technology, Huangdao Zone, Qindao, Shandong
Hotechem Shanghai Co., Ltd

Contact:13120882795；+86-21-34621078;+86-021-31122318

Address:Suite 2,No.2715 Longwu Road

Relevant to this article

Stereoselective syntheses of the 2-isopropenyl-2,3-dihydrobenzofuran nucleus: Potential chiral building blocks for the syntheses of tremetone, hydroxytremetone, and rotenone

Doi:10.1021/jo062447h
(2007)
Doi:10.1038/labinvest.3780404
()
Doi:10.1007/BF00929554
(1960)
Efficient synthesis of 3-benzyl-3-(indol-3-yl)-2-phenyl-2,3- dihydroisoindolinone derivatives via a simple and convenient MCR in aqueous micellar system

Doi:10.1016/j.tetlet.2013.05.151
(2013)
Ring-opening reaction of 2,5-dioctyldithieno[2,3-b:3',2'-d]thiophene in the presence of aryllithium reagents

Doi:10.3762/bjoc.9.87
(2013)
Copper-catalyzed allylic alkylations of alkylzirconium intermediates

Doi:10.1016/S0040-4039(00)61072-9
(1992)

Article Doi