Tetrahedron p. 5031 - 5038 (1987)
Update date:2022-08-04
Topics:
Barbier, Michael
Barton, Derek H. R.
Devys, Michel
Topgi, Ravindra Satish
Cyclohexa-2,4- and 2,5-dienones bearing position 2 or 4 a dihalomethyl group (halogen = chlorine or bromine) are smoothly reduced by tri-butyltin hydride to furnish appropriately substituted tropones.Modification of the substituents permits access to a tropolone and to less substituted tropones.The mechanism of this ring expansion process has been discussed.
View MoreCGeneTech (Suzhou, China) Co., Ltd.
Contact:+86-512-62956962
Address:Room 101，Bld C11,218 Xinghu Rd.,Suzhou industrial Park
RongCheng K&S Chemical Co.,Ltd
Contact:0631-7336369
Address:rongcheng ,shandong province china
Contact:+86-021-50792271
Address:Building 24A, 300 Chuantu Road, Chuansha, Pudong new area, Shanghai, China, 201202
Contact:86-10-62664360
Address:Building 10,No.18 AnNingZhuang East Road, GuangHua Pioneer Park,HaiDian District, BeiJing China
Hangzhou Yanshan Chemical Co.,Ltd.
Contact:86-571- 87698076
Address:Room 1001, #1 Building, Zhongtian MCC, No.2 Youzhinong, Wenyi West Road, Xihu District, Hangzhou, China
Doi:10.1002/jhet.392
(2010)Doi:10.1021/jo01025a513
(1964)Doi:10.1021/ol070482k
(2007)Doi:10.1021/jo00202a007
(1985)Doi:10.1021/ja0675898
(2007)Doi:10.1016/S0040-4020(97)10198-3
(1997)
