BRANCHED-CHAIN SUGARS. XXXV. THE SYNTHESIS OF L-RUBRANITROSE (2,3,6-TRIDEOXY-3-C-METHYL-4-O-METHYL-3-NITRO-L-XYLO-HEXOPYRANOSE).

DOI: 10.1246/bcsj.57.2535

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2535 - 2537 (1984)

Update date:2022-08-02

Topics:

Authors:

Yoshimura

Yasumori

Kondo Kondo

Sato Sato

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Article abstract of DOI:10.1246/bcsj.57.2535

The compound was stereoselectively synthesized from methyl 2,6-dideoxy-4-O-methyl- beta -L-threo-hexopyranosid-3-ulose through the successive conversions; cyanomesylation, reductive spiro aziridine formation, reductive ring-opening to the methyl-branched amino sugar, oxidation to the corresponding nitro sugar.

Full text of DOI:10.1246/bcsj.57.2535

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