Fluorodiazadiphosphetidines, XIII: The Reaction of 2,2,2,4,4,4-Hexafluoro-1,3-dimethyl-1,3,2λ5,4λ5-diazadiphosphetidines with Alcohols

DOI: 10.1007/BF00798756

Source and publish data:

Monatshefte fur Chemie p. 881 - 898 (1984)

Update date:2022-08-04

Topics: Alcohols Reaction Experimental

Authors:

Hahn, Heinrich

Toifl, Erich

Meindl, Wolfgang

Utvary, Kurt

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Article abstract of DOI:10.1007/BF00798756

Nucleophilic substitution reactions of (CH3NPF3)2 with alcohols have been studied.In case of (CH3NPF3)2 as starting material an excess of this compound acts as an HF-acceptor.In this way mono- or di-alkoxysubstituted diazaphosphetidines are obtained.If the starting material is a substituted ring or if an aromatic alcohol is employed, the alcohol component has to be in form of the lithium salt. - Keywords: Aza; Cyclic (non-carbon); Heterocyclic (N,P); Phospha; Alcohol

Full text of DOI:10.1007/BF00798756

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