Chemistry Letters p. 1623 - 1624 (1984)
Update date:2022-08-03
Topics: Regioselectivity Catalyst Nucleophile Chromatography Workup Reaction Mechanism Solvent Effects Activation Energy Spectroscopic Analysis Aromatic substitution Nitroarenes Electron-Withdrawing Group (EWG)
Makosza, Mieczyslaw
Winiarski, Jerzy
Carbanion of phenyl trithioorthoformate reacts with nitroarenes according to the vicarious substitution scheme replacing hydrogen in the para position to the nitro group.The reaction offers a new method of nucleophilic formylation of nitroarenes.
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