Carbon monoxide activation by iridium(III) dicationic carbonyl complexes

DOI: 10.1021/om00122a029

Source and publish data:

Organometallics p. 590 - 598 (1985)

Update date:2022-08-04

Topics:

Authors:

Lilga, Michael A.

Ibers, James A.

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Article abstract of DOI:10.1021/om00122a029

The cationic cis- and trans-IrX(CO)(dppe)₂²⁺ (X = H, Cl) species react with nucleophiles, such as H₂O, OH^-, and H^-, to afford hydroxycarbonyl and formyl cations of Ir(III) typified by the species tran

Full text of DOI:10.1021/om00122a029

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Product name:IrCl(CO)(((C₆H₅)2PCH₂)2)2⁽²⁺⁾*2SO₃CF₃^(1-) = [IrCl(CO)(((C₆H₅)2PCH₂)2)2](SO₃CF₃)2

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