Thermal 2,5-Cycloaddition of N-Arylmaleimides to Phenols

DOI: 10.1039/c39840000951

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 951 - 952 (1984)

Update date:2022-09-26

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Authors:

Bryce-Smith, Derek

Gilbert, Andrew

McColl, Ian S.

Yianni, Paul

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Article abstract of DOI:10.1039/c39840000951

Phenol undergoes thermal 2,5-cycloaddition of N-phenylmaleimide to give endo- and exo-bicyclo-octenones (3) and (4) respectively, and a homopolymer of the maleimide; use of N-(p-methoxyphenyl)maleimide minimises polymer formation, and gives a combined cycloadduct yield of 60percent in the case of p-cresol.

Full text of DOI:10.1039/c39840000951

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