Journal of the Chemical Society. Chemical communications p. 951 - 952 (1984)
Update date:2022-09-26
Topics:
Bryce-Smith, Derek
Gilbert, Andrew
McColl, Ian S.
Yianni, Paul
Phenol undergoes thermal 2,5-cycloaddition of N-phenylmaleimide to give endo- and exo-bicyclo-octenones (3) and (4) respectively, and a homopolymer of the maleimide; use of N-(p-methoxyphenyl)maleimide minimises polymer formation, and gives a combined cycloadduct yield of 60percent in the case of p-cresol.
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