Journal of the Chemical Society. Chemical communications p. 1525 - 1526 (1984)
Update date:2022-08-04
Topics:
Michalczyk, Michael J.
West, Robert
Michl, Josef
Reaction of trans-1,2-di-t-butyl-1,2-dimesityldisilaethylene in solution with dioxygen at -78 deg C produces the disiloxirane (7) and a compound believed to be the 1,2-disiladioxetane (8a); the latter compound rearranges quantitatively to the known 1,3-cyclodisiloxane (5) above 0 deg C.
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Doi:10.1021/jo01040a518
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